Chip package structure with conductive adhesive layer and method for forming the same

ABSTRACT

A method for forming a chip package structure is provided. The method includes providing a wiring substrate including a substrate, a pad, and a polymer layer. The polymer layer is over the substrate and the pad, and the polymer layer has a first opening exposing the pad. The method includes forming a conductive adhesive layer over the polymer layer and the pad. The conductive adhesive layer is in direct contact with and conformally covers the polymer layer and the pad. The method includes forming a nickel layer over the conductive adhesive layer. The nickel layer is thicker than the conductive adhesive layer, and the nickel layer and the conductive adhesive layer are made of different materials. The method includes bonding a chip to the wiring substrate through a conductive bump. The conductive bump is between the nickel layer and the chip.

BACKGROUND

Semiconductor devices are used in a variety of electronic applications, such as personal computers, cell phones, digital cameras, and other electronic equipment. Semiconductor devices are typically fabricated by sequentially depositing insulating or dielectric layers, conductive layers, and semiconductor layers over a semiconductor substrate, and patterning the various material layers using lithography to form circuit components and elements.

Dozens or hundreds of integrated circuits are typically manufactured on a single semiconductor wafer. The individual dies are singulated by sawing the integrated circuits along scribe lines. The individual dies are then packaged separately. The semiconductor industry continues to improve the integration density of various electronic components (e.g., transistors, diodes, resistors, capacitors, etc.) by continual reductions in minimum feature size, which allow more components to be integrated into a given area. However, since feature sizes continue to decrease, fabrication processes continue to become more difficult to perform. Therefore, it is a challenge to form reliable packages with electronic components with high integration density.

BRIEF DESCRIPTION OF THE DRAWINGS

Aspects of the present disclosure are best understood from the following detailed description when read with the accompanying figures. It should be noted that, in accordance with standard practice in the industry, various features are not drawn to scale. In fact, the dimensions of the various features may be arbitrarily increased or reduced for clarity of discussion.

FIGS. 1A-1E are cross-sectional views of various stages of a process for forming a chip package structure, in accordance with some embodiments.

FIG. 2 is a cross-sectional view of a stage of a process for forming a chip package structure, in accordance with some embodiments.

FIGS. 3A-3C are cross-sectional views of various stages of a process for forming a chip package structure, in accordance with some embodiments.

FIG. 4 is a cross-sectional view of a stage of a process for forming a chip package structure, in accordance with some embodiments.

FIGS. 5A-5D are cross-sectional views of various stages of a process for forming a chip package structure, in accordance with some embodiments.

FIGS. 6A-6E are cross-sectional views of various stages of a process for forming a chip package structure, in accordance with some embodiments.

FIGS. 7A-7C are cross-sectional views of various stages of a process for forming a chip package structure, in accordance with some embodiments.

FIGS. 8A-8D are cross-sectional views of various stages of a process for forming a chip package structure, in accordance with some embodiments.

FIGS. 9A-9C are cross-sectional views of various stages of a process for forming a chip package structure, in accordance with some embodiments.

FIGS. 10A-10C are cross-sectional views of various stages of a process for forming a chip package structure, in accordance with some embodiments.

FIGS. 11A-11C are cross-sectional views of various stages of a process for forming a chip package structure, in accordance with some embodiments.

DETAILED DESCRIPTION

The following disclosure provides many different embodiments, or examples, for implementing different features of the subject matter provided. Specific examples of components and arrangements are described below to simplify the present disclosure. These are, of course, merely examples and are not intended to be limiting. For example, the formation of a first feature over or on a second feature in the description that follows may include embodiments in which the first and second features are formed in direct contact, and may also include embodiments in which additional features may be formed between the first and second features, such that the first and second features may not be in direct contact. In addition, the present disclosure may repeat reference numerals and/or letters in the various examples. This repetition is for the purpose of simplicity and clarity and does not in itself dictate a relationship between the various embodiments and/or configurations discussed.

Furthermore, spatially relative terms, such as “beneath,” “below,” “lower,” “above,” “upper” and the like, may be used herein for ease of description to describe one element or feature's relationship to another element(s) or feature(s) as illustrated in the figures. The spatially relative terms are intended to encompass different orientations of the device in use or operation in addition to the orientation depicted in the figures. The apparatus may be otherwise oriented (rotated 90 degrees or at other orientations) and the spatially relative descriptors used herein may likewise be interpreted accordingly. It should be understood that additional operations can be provided before, during, and after the method, and some of the operations described can be replaced or eliminated for other embodiments of the method.

Some embodiments of the disclosure are described. Additional operations can be provided before, during, and/or after the stages described in these embodiments. Some of the stages that are described can be replaced or eliminated for different embodiments. Additional features can be added to the semiconductor device structure. Some of the features described below can be replaced or eliminated for different embodiments. Although some embodiments are discussed with operations performed in a particular order, these operations may be performed in another logical order.

FIGS. 1A-1E are cross-sectional views of various stages of a process for forming a chip package structure, in accordance with some embodiments. As shown in FIG. 1A, a wiring substrate 110 is provided, in accordance with some embodiments. The wiring substrate 110 includes a substrate 111, through substrate vias (or plated through holes, PTH) 112, wiring layers 113 a, 113 b, 114 a and 114 b, pads 115 a and 115 b, conductive vias 116 a and 116 b, insulating layers 117 a and 117 b, and polymer layers 118 a and 118 b, in accordance with some embodiments.

The substrate 111 has surfaces 111 a and 111 b, in accordance with some embodiments. The surface 111 a is opposite to the surface 111 b, in accordance with some embodiments. In some embodiments, the substrate 111 is made of an insulating material such as a fiber material, a polymer material (e.g., a polymer organic material), or a glass material. The fiber material includes, for example, a glass fiber material.

In some other embodiments, the substrate 111 is made of a semiconductor material or a conductive material, in accordance with some embodiments. The semiconductor material includes, for example, silicon or germanium. The conductive material includes, for example, a metal material.

The through substrate vias 112 pass through the substrate 111, in accordance with some embodiments. The wiring layers 113 a and 113 b are formed over the surfaces 111 a and 111 b respectively, in accordance with some embodiments. The through substrate vias 112 electrically connect the wiring layer 113 a to the wiring layer 113 b, in accordance with some embodiments.

If the substrate 111 is made of a semiconductor material or a conductive material, an insulating layer (not shown) is formed between the substrate 111 and the through substrate vias 112 and between the substrate 111 and the wiring layers 113 a and 113 b to electrically insulate the substrate 111 from the through substrate vias 112 and the wiring layers 113 a and 113 b, in accordance with some embodiments.

The wiring layer 114 a, the pads 115 a, the conductive vias 116 a, the insulating layer 117 a, and the polymer layer 118 a are formed over the surface 111 a, in accordance with some embodiments. The wiring layer 114 a and the conductive vias 116 a are in the insulating layer 117 a, in accordance with some embodiments. The pads 115 a are positioned over the insulating layer 117 a, in accordance with some embodiments. The conductive vias 116 a are electrically connected between the wiring layers 113 a and 114 a and between the wiring layer 114 a and the pads 115 a, in accordance with some embodiments.

The polymer layer 118 a is formed over the insulating layer 117 a and the pads 115 a, in accordance with some embodiments. The polymer layer 118 a has openings P1, in accordance with some embodiments. The openings P1 respectively expose the pads 115 a thereunder, in accordance with some embodiments. The polymer layer 118 a partially covers the pads 115 a, in accordance with some embodiments.

The polymer layer 118 a is a solder resist layer, an Ajinomoto build-up film (ABF), or a prepreg (PP), in accordance with some embodiments. The solder resist layer is made of a solder resist (SR) material, in accordance with some embodiments. The polymer layer 118 a is made of any suitable polymer material, such as resin or polyimide, in accordance with some embodiments.

The wiring layer 114 b, the pads 115 b, the conductive vias 116 b, the insulating layer 117 b, and the polymer layer 118 b are formed over the surface 111 b, in accordance with some embodiments. The wiring layer 114 b and the conductive vias 116 b are in the insulating layer 117 b, in accordance with some embodiments. The pads 115 b are over the insulating layer 117 b, in accordance with some embodiments. The conductive vias 116 b are electrically connected between the wiring layers 113 b and 114 b and between the wiring layer 114 b and the pads 115 b, in accordance with some embodiments.

The polymer layer 118 b is formed over the insulating layer 117 b and the pads 115 b, in accordance with some embodiments. The polymer layer 118 b has openings P2, in accordance with some embodiments. The openings P2 respectively expose the pads 115 b, in accordance with some embodiments. The polymer layer 118 b partially covers the pads 115 b, in accordance with some embodiments.

The polymer layer 118 b is a solder resist layer, an Ajinomoto build-up film (ABF), or a prepreg (PP), in accordance with some embodiments. The solder resist layer is made of a solder resist (SR) material, in accordance with some embodiments. The polymer layer 118 b is made of any suitable polymer material, such as resin or polyimide, in accordance with some embodiments.

In some embodiments, the pad 115 a is narrower than the pad 115 b. That is, a width W1 of the pad 115 b is greater than a width W2 of the pad 115 a, in accordance with some embodiments. The width W1 ranges from about 200 μm to about 600 μm, in accordance with some embodiments. The width W2 ranges from about 20 μm to about 110 in accordance with some embodiments. In some embodiments, a (maximum) width W3 of the opening P2 is greater than a (maximum) width W4 of the opening P1.

The through substrate vias 112, the wiring layers 113 a, 113 b, 114 a and 114 b, the pads 115 a and 115 b, and the conductive vias 116 a and 116 b are made of a conductive material such as a metal material or an alloy thereof, in accordance with some embodiments. The metal material includes aluminum, copper or tungsten, in accordance with some embodiments.

As shown in FIG. 1A, a conductive adhesive material layer 120 a is formed over the polymer layer 118 a and the pads 115 a, in accordance with some embodiments. The conductive adhesive material layer 120 a conformally covers a top surface 118 a 1 of the polymer layer 118 a, inner walls S of the openings P1, and top surfaces 115 a 1 of the pads 115 a, in accordance with some embodiments.

The conductive adhesive material layer 120 a is in direct contact with the polymer layer 118 a and the pads 115 a, in accordance with some embodiments. The conductive adhesive material layer 120 a passes through the polymer layer 118 a, in accordance with some embodiments. The conductive adhesive material layer 120 a is a single layer structure, in accordance with some embodiments. In some other embodiments, the conductive adhesive material layer 120 a is a multilayer structure.

The conductive adhesive material layer 120 a is made of nickel (Ni), titanium (Ti), copper (Cu), palladium (Pd), an alloy thereof, a combination thereof, or another suitable metal or alloy, in accordance with some embodiments. The conductive adhesive material layer 120 a is formed using a deposition process (e.g., a sputtering process) or a plating process (e.g., an electroless plating process), in accordance with some embodiments.

As shown in FIG. 1B, a mask layer 130 is formed over the conductive adhesive material layer 120 a, in accordance with some embodiments. The mask layer 130 has openings 132, in accordance with some embodiments. The openings 132 expose the conductive adhesive material layer 120 a over or adjacent to the pads 115 a, in accordance with some embodiments. The mask layer 130 is made of a photoresist material, such as a polymer material, in accordance with some embodiments.

As shown in FIG. 1B, a solder layer 140 a is formed in the openings 132, in accordance with some embodiments. The solder layer 140 a is formed over the conductive adhesive material layer 120 a, in accordance with some embodiments. The solder layer 140 a is in direct contact with the conductive adhesive material layer 120 a, in accordance with some embodiments.

The solder layer 140 a is made of a suitable solder material, such as tin (Sn) or tin alloy, in accordance with some embodiments. The solder layer 140 a is formed using a plating process, such as an electroplating process, in accordance with some embodiments. The conductive adhesive material layer 120 a is used as a seed layer in the electroplating process, in accordance with some embodiments.

As shown in FIGS. 1B-1C, the mask layer 130 and the conductive adhesive material layer 120 a under the mask layer 130 are removed, in accordance with some embodiments. The conductive adhesive material layer 120 a remaining under the solder layer 140 a forms a conductive adhesive layer 120, in accordance with some embodiments. The conductive adhesive layer 120 is able to improve the adhesion between the solder layer 140 a and the polymer layer 118 a and between the solder layer 140 a and the pads 115 a, in accordance with some embodiments.

As shown in FIG. 1D, a reflow process is performed over the solder layer 140 a, in accordance with some embodiments. The reflowed solder layer 140 a forms solder structures 140, in accordance with some embodiments. The solder structures 140 have top surfaces 142, in accordance with some embodiments. The top surfaces 142 are curved top surfaces, in accordance with some embodiments. The process temperature of the reflow process ranges from about 200° C. to about 300° C., in accordance with some embodiments.

As shown in FIG. 1E, a thermo-compression process is performed over the solder structures 140 to flatten the top surfaces 142 of the solder structures 140, in accordance with some embodiments. The process temperature of the thermo-compression process ranges from about 50° C. to about 150° C., in accordance with some embodiments.

In some embodiments, the conductive adhesive layer 120 is a single layer structure, in accordance with some embodiments. In some other embodiments, as shown in FIG. 2, the conductive adhesive layer 120 is a multilayer structure, in accordance with some embodiments. The conductive adhesive layer 120 includes layers 122 and 124, in accordance with some embodiments.

In some embodiments, the layer 122 is made of copper, and the layer 124 is made of nickel, in accordance with some embodiments. In some other embodiments, the layer 122 is made of titanium, and the layer 124 is made of copper, in accordance with some embodiments. In still other embodiments, the layer 122 is made of palladium, and the layer 124 is made of copper, in accordance with some embodiments.

FIGS. 3A-3C are cross-sectional views of various stages of a process for forming a chip package structure, in accordance with some embodiments. As shown in FIG. 3A, after the step of FIG. 1A, a mask layer 310 is formed over the conductive adhesive material layer 120 a over or adjacent to the pads 115 a, in accordance with some embodiments. The mask layer 310 is also referred to as a dry film, in accordance with some embodiments. The mask layer 310 is made of a polymer material, in accordance with some embodiments.

As shown in FIGS. 3A-3B, the conductive adhesive material layer 120 a exposed by the mask layer 310 is removed, in accordance with some embodiments. The conductive adhesive material layer 120 a remaining under the mask layer 310 forms a conductive adhesive layer 120, in accordance with some embodiments.

As shown in FIG. 3C, the mask layer 310 is removed, in accordance with some embodiments. As shown in FIG. 3C, a mask layer 320 is formed over the polymer layer 118 a, in accordance with some embodiments. The mask layer 320 has openings 322 exposing the conductive adhesive layer 120, in accordance with some embodiments. The mask layer 320 is made of a photoresist material, such as a polymer material, in accordance with some embodiments.

As shown in FIG. 3C, a printing process is performed to form a solder layer 140 b in the openings 322, in accordance with some embodiments. The solder layer 140 b is made of a suitable solder material, such as tin (Sn) or tin alloy, in accordance with some embodiments. Thereafter, as shown in FIG. 1D, the mask layer 320 is removed and a reflow process is performed over the solder layer 140 b to form solder structures 140, in accordance with some embodiments.

FIG. 4 is a cross-sectional view of a stage of a process for forming a chip package structure, in accordance with some embodiments. As shown in FIG. 4, after the step of FIG. 3B, the mask layer 310 is removed, in accordance with some embodiments. As shown in FIG. 4, solder balls 140 c are disposed over the conductive adhesive layer 120, in accordance with some embodiments. Thereafter, as shown in FIG. 1D, the solder balls 140 c are reflowed to form solder structures 140, in accordance with some embodiments.

FIGS. 5A-5D are cross-sectional views of various stages of a process for forming a chip package structure, in accordance with some embodiments. As shown in FIG. 5A, after the step of FIG. 1E, a chip 510 is provided, in accordance with some embodiments. The chip 510 includes a semiconductor substrate 511, elements 512, a dielectric layer 513, an interconnection layer 514, conductive pads 515, an insulating layer 516, and a buffer layer 517, in accordance with some embodiments.

The semiconductor substrate 511 has a front surface 511 a and a back surface 511 b opposite to the front surface 511 a, in accordance with some embodiments. In some embodiments, the semiconductor substrate 511 is made of at least an elementary semiconductor material including silicon or germanium in a single crystal, polycrystal, or amorphous structure. In some other embodiments, the semiconductor substrate 511 is made of a compound semiconductor, such as silicon carbide, gallium arsenide, gallium phosphide, indium phosphide, indium arsenide, an alloy semiconductor, such as SiGe, or GaAsP, or a combination thereof. The semiconductor substrate 511 may also include multi-layer semiconductors, semiconductor on insulator (SOI) (such as silicon on insulator or germanium on insulator), or a combination thereof.

In some embodiments, the elements 512 are formed over the front surface 511 a or in the semiconductor substrate 511 adjacent to the front surface 511 a. The elements 512 include active elements (e.g. transistors, diodes, or the like) and/or passive elements (e.g. resistors, capacitors, inductors, or the like), in accordance with some embodiments.

The dielectric layer 513 is formed over the front surface 511 a and the elements 512, in accordance with some embodiments. The dielectric layer 513 is made of oxide material such as silicon oxide, in accordance with some embodiments. In some other embodiments, the dielectric layer 513 is made of a polymer material, such as polybenzoxazole (PBO), polyimide, benzocyclobutene (BCB), epoxy, a photo-sensitive material, or another suitable material.

The interconnection layer 514 is formed over the dielectric layer 513, in accordance with some embodiments. The interconnection layer 514 includes dielectric layers (not shown) and conductive interconnection structures (not shown) in the dielectric layers, in accordance with some embodiments.

The conductive pads 515 are formed over the interconnection layer 514, in accordance with some embodiments. The conductive pads 515 are electrically connected to the elements 512 through the interconnection layer 514, in accordance with some embodiments. The conductive pads 515 are made of a conductive material, such as copper (Cu), copper alloy, aluminum (Al), aluminum alloy, tungsten (W), tungsten alloy, titanium (Ti), titanium alloy, tantalum (Ta) or tantalum alloy, in accordance with some embodiments.

The insulating layer 516 is formed over the interconnection layer 514 and peripheral portions of the conductive pads 515, in accordance with some embodiments. The insulating layer 516 has openings 516 a exposing central portions of the conductive pads 515, in accordance with some embodiments.

The insulating layer 516 is made of a dielectric material, such as undoped silicate glass (USG), silicon nitride, silicon oxide, or silicon oxynitride, in accordance with some embodiments. The insulating layer 516 is formed using a deposition process (e.g., a chemical vapor deposition process or a physical vapor deposition process) and an etching process, in accordance with some embodiments.

The buffer layer 517 is formed over the insulating layer 516, in accordance with some embodiments. The buffer layer 517 is further formed over the peripheral portions of the conductive pads 515, in accordance with some embodiments.

The buffer layer 517 has openings 517 a exposing central portions of the conductive pads 515, in accordance with some embodiments. The buffer layer 517 is used to buffer the bonding stress from bumps subsequently formed over the conductive pads 515 during subsequent bonding processes, in accordance with some embodiments.

The buffer layer 517 is made of a material softer than the insulating layer 516 and/or the conductive pads 515, in accordance with some embodiments. The buffer layer 517 is made of a polymer material such as epoxy, polyimide, benzocyclobutene (BCB), polybenzoxazole (PBO), or another suitable material, in accordance with some embodiments.

As shown in FIG. 5A, an under bump metallurgy (UBM) layer 520 is formed over the conductive pads 515 and the buffer layer 517 adjacent to the conductive pads 515, in accordance with some embodiments. The under bump metallurgy layer 520 is made of titanium, titanium nitride, tantalum, tantalum nitride, copper, or copper alloy including silver, chromium, nickel, tin and/or gold, in accordance with some embodiments.

As shown in FIG. 5A, solder structures 530 a are formed over the under bump metallurgy layer 520, in accordance with some embodiments. The solder structures 530 a are made of a suitable solder material, such as tin (Sn) or tin alloy, in accordance with some embodiments.

As shown in FIG. 5B, the chip 510 is bonded to the wiring substrate 110 through conductive bumps 530, in accordance with some embodiments. The conductive bumps 530 are between and connected to the conductive adhesive layer 120 and the under bump metallurgy layer 520, in accordance with some embodiments. In some embodiments, the conductive bumps 530 are formed from the solder structures 140 and 530 a in FIGS. 1E and 5A.

In some embodiments, a thickness T1 of the conductive adhesive layer 120 is substantially equal to a thickness T2 of the under bump metallurgy layer 520. The thickness T1 ranges from about 0.5 μm to about 2 μm, in accordance with some embodiments. The thickness T2 ranges from about 0.5 μm to about 2 μm, in accordance with some embodiments.

The term “substantially equal to” in the application means “within 10%”, in accordance with some embodiments. For example, the term “substantially equal to” means the difference between the thicknesses T1 and T2 is within 10% of the average thickness between the under bump metallurgy layer 520 and the conductive adhesive layer 120, in accordance with some embodiments. The difference may be due to manufacturing processes.

Since the thickness T1 is substantially equal to the thickness T2, the tensile stress applied by the conductive adhesive layer 120 to the conductive bumps 530 is substantially equal to the tensile stress applied by the under bump metallurgy layer 520 to the conductive bumps 530, in accordance with some embodiments. As a result, in the conductive bumps 530, the tensile stresses applied by the conductive adhesive layer 120 and the under bump metallurgy layer 520 are substantially balanced, in accordance with some embodiments.

The tensile stress balance prevents the conductive bumps 530 from developing cracks, in accordance with some embodiments. Therefore, the yield of the conductive bumps 530 is improved, in accordance with some embodiments. The yield of a chip package structure with the conductive adhesive layer 120, the under bump metallurgy layer 520, and the conductive bumps 530 is also improved, in accordance with some embodiments.

As shown in FIG. 5B, an underfill layer U is formed between the chip 510 and the wiring substrate 110, in accordance with some embodiments. The underfill layer U surrounds the conductive bumps 530, in accordance with some embodiments. The underfill layer U includes an insulating material, such as a polymer material, in accordance with some embodiments.

As shown in FIG. 5B, an adhesive layer 540 is formed over the wiring substrate 110, in accordance with some embodiments. The adhesive layer 540 surrounds the chip 510 and the underfill layer U, in accordance with some embodiments. The adhesive layer 540 has a ring shape, in accordance with some embodiments. The adhesive layer 540 is made of polymer, such as epoxy or silicone, in accordance with some embodiments. The adhesive layer 540 is formed using a dispensing process, in accordance with some embodiments.

As shown in FIG. 5B, an adhesive layer 541 is formed over the chip 510, in accordance with some embodiments. The adhesive layer 541 is made of a silver paste, a tin paste, a mixture of metal powder and polymer, or another suitable adhesive material with good thermal conductivity, in accordance with some embodiments. The adhesive layer 541 is formed using a dispensing process, in accordance with some embodiments.

As shown in FIG. 5B, a heat-spreading lid 550 is disposed over the chip 510 and the adhesive layers 540 and 541, in accordance with some embodiments. The heat-spreading lid 550 is made of a high thermal conductivity material, such as a metal material (aluminum or copper), an alloy material (e.g., stainless steel), or aluminum-silicon carbide (AlSiC), in accordance with some embodiments. In some other embodiments, the adhesive layers 540 and 541 are formed over the heat-spreading lid 550 firstly, and then the heat-spreading lid 550 and the adhesive layers 540 and 541 are disposed over the chip 510 and the wiring substrate 110.

As shown in FIG. 5C, conductive bumps 560 are formed over the pads 115 b and in the openings P2, in accordance with some embodiments. The conductive bumps 560 are made of a suitable solder material, such as tin (Sn) or tin alloy, in accordance with some embodiments.

As shown in FIG. 5C, a cutting process is performed over the wiring substrate 110 along cutting lines A to cut through the wiring substrate 110 to form chip package structures 500, in accordance with some embodiments.

As shown in FIG. 5D, the chip package structure 500 is bonded to a wiring substrate 570 through the conductive bumps 560, in accordance with some embodiments. The wiring substrate 570 includes an insulating layer 572, wiring layers 574, conductive vias 576, and pads 578, in accordance with some embodiments.

The wiring layers 574 and the conductive vias 576 are in the insulating layer 572, in accordance with some embodiments. The pads 578 are over the insulating layer 572, in accordance with some embodiments. The conductive vias 576 are electrically connected between the wiring layers 574 and between the wiring layer 574 and the pads 578, in accordance with some embodiments.

The wiring layers 574, the conductive vias 576, and the pads 578 are made of a conductive material such as a metal material or an alloy thereof, in accordance with some embodiments. The metal material includes aluminum, copper or tungsten.

In this step, a chip package structure (or board-level package structure) 501 is substantially formed, in accordance with some embodiments. The chip package structure 501 includes the chip package structure 500, the conductive bumps 560, and the wiring substrate 570, in accordance with some embodiments. The chip package structure 501 is a ball grid array (BGA) package structure, in accordance with some embodiments.

FIGS. 6A-6E are cross-sectional views of various stages of a process for forming a chip package structure, in accordance with some embodiments. As shown in FIG. 6A, the step of FIG. 6A is similar to the step of FIG. 1A, except that the step of FIG. 6A further forms a conductive adhesive material layer 610 a over the polymer layer 118 b and the pads 115 b during forming the conductive adhesive material layer 120 a over the polymer layer 118 a and the pads 115 a, in accordance with some embodiments.

In some embodiments, the conductive adhesive material layers 120 a and 610 a are made of the same material. The conductive adhesive material layer 610 a is made of nickel (Ni), titanium (Ti), copper (Cu), palladium (Pd), an alloy thereof, a combination thereof, or another suitable metal or alloy, in accordance with some embodiments. The conductive adhesive material layer 610 a is formed using a deposition process, such as an electroless plating process, in accordance with some embodiments.

In some other embodiments (not shown), the conductive adhesive material layers 120 a and 610 a are formed in different processes. The conductive adhesive material layers 120 a and 610 a are made of different materials, in accordance with some embodiments.

As shown in FIG. 6B, the steps of FIGS. 1B-1E and 5A-5B are performed to form the conductive adhesive layer 120, the chip 510, the under bump metallurgy layer 520, the conductive bumps 530, the underfill layer U, the adhesive layer 540, and the heat-spreading lid 550 over the wiring substrate 110, in accordance with some embodiments.

As shown in FIG. 6C, the wiring substrate 110 is flipped upside down, in accordance with some embodiments. As shown in FIG. 6C, a mask layer 620 is formed over the conductive adhesive material layer 610 a, in accordance with some embodiments. The mask layer 620 has openings 622, in accordance with some embodiments. The openings 622 expose the conductive adhesive material layer 610 a over or adjacent to the pads 115 b, in accordance with some embodiments. The mask layer 620 is made of a photoresist material, such as a polymer material, in accordance with some embodiments.

As shown in FIG. 6C, a solder layer 560 a is formed in the openings 622, in accordance with some embodiments. The solder layer 560 a is formed over the conductive adhesive material layer 610 a, in accordance with some embodiments. The solder layer 560 a is in direct contact with the conductive adhesive material layer 610 a, in accordance with some embodiments.

The solder layer 560 a is made of a suitable solder material, such as tin (Sn) or tin alloy, in accordance with some embodiments. The solder layer 560 a is formed using a plating process, such as an electroplating process, in accordance with some embodiments. The conductive adhesive material layer 610 a is used as a seed layer in the electroplating process, in accordance with some embodiments.

As shown in FIGS. 6C-6D, the mask layer 620 and the conductive adhesive material layer 610 a under the mask layer 620 are removed, in accordance with some embodiments. The conductive adhesive material layer 610 a remaining under the solder layer 560 a forms a conductive adhesive layer 610, in accordance with some embodiments.

As shown in FIG. 6D, a reflow process is performed over the solder layer 560 a, in accordance with some embodiments. The reflowed solder layer 560 a forms conductive bumps 560, in accordance with some embodiments. The conductive bumps 560 have ball-like shapes, in accordance with some embodiments.

As shown in FIG. 6D, a cutting process is performed over the wiring substrate 110 along cutting lines A to cut through the wiring substrate 110 to form chip package structures 600, in accordance with some embodiments.

As shown in FIG. 6E, the chip package structure 600 is bonded to a wiring substrate 570 through the conductive bumps 560, in accordance with some embodiments. The wiring substrate 570 includes an insulating layer 572, wiring layers 574, conductive vias 576, and pads 578, in accordance with some embodiments.

The wiring layers 574 and the conductive vias 576 are in the insulating layer 572, in accordance with some embodiments. The pads 578 are over the insulating layer 572, in accordance with some embodiments. The conductive vias 576 are electrically connected between the wiring layers 574 and between the wiring layer 574 and the pads 578, in accordance with some embodiments.

The wiring layers 574, the conductive vias 576, and the pads 578 are made of a conductive material such as a metal material or an alloy thereof, in accordance with some embodiments. The metal material includes aluminum, copper or tungsten.

In this step, a chip package structure (or board-level package structure) 601 is substantially formed, in accordance with some embodiments. The chip package structure 601 includes the chip package structure 600, the conductive bumps 560, and the wiring substrate 570, in accordance with some embodiments.

In some embodiments, as shown in FIGS. 6A-6D, the conductive adhesive layer 610 is formed by depositing the conductive adhesive material layer 610 a and removing the conductive adhesive material layer 610 a under the mask layer 620. In some other embodiments (e.g., embodiments of FIGS. 7A-7B), the conductive adhesive layer 610 is formed by depositing the conductive adhesive material layer 610 a and removing the conductive adhesive material layer 610 a exposed by a mask layer.

FIGS. 7A-7C are cross-sectional views of various stages of a process for forming a chip package structure, in accordance with some embodiments. As shown in FIG. 7A, after the step of FIG. 6B, the wiring substrate 110 is flipped upside down, in accordance with some embodiments. As shown in FIG. 7A, a mask layer 710 is formed over the conductive adhesive material layer 610 a over or adjacent to the pads 115 b, in accordance with some embodiments. The mask layer 710 is also referred to as a dry film, in accordance with some embodiments. The mask layer 710 is made of a polymer material, in accordance with some embodiments.

As shown in FIGS. 7A-7B, the conductive adhesive material layer 610 a exposed by the mask layer 710 is removed, in accordance with some embodiments. The conductive adhesive material layer 610 a remaining under the mask layer 710 forms a conductive adhesive layer 610, in accordance with some embodiments. As shown in FIG. 7B, the mask layer 710 is removed, in accordance with some embodiments.

Thereafter, as shown in FIG. 7C, conductive bumps 560 are formed over the conductive adhesive layer 610, in accordance with some embodiments. The conductive bumps 560 are formed using a printing process (similar to the printing process of FIG. 3C) or a ball mounting process (similar to the ball mounting process of FIG. 4) and a reflow process, in accordance with some embodiments.

As shown in FIG. 7C, a cutting process is performed over the wiring substrate 110 along cutting lines A to cut through the wiring substrate 110 to form chip package structures 700, in accordance with some embodiments.

FIGS. 8A-8D are cross-sectional views of various stages of a process for forming a chip package structure, in accordance with some embodiments. As shown in FIG. 8A, a wiring substrate 110 is provided, in accordance with some embodiments. As shown in FIG. 8A, a material layer 122 a is formed over the polymer layer 118 a and the pads 115 a, in accordance with some embodiments.

The material layer 122 a conformally covers a top surface 118 a 1 of the polymer layer 118 a, inner walls S of openings P1 of the polymer layer 118 a, and top surfaces 115 a 1 of the pads 115 a, in accordance with some embodiments. The material layer 122 a is in direct contact with the polymer layer 118 a and the pads 115 a, in accordance with some embodiments.

As shown in FIG. 8A, a material layer 124 a is formed over the material layer 122 a, in accordance with some embodiments. The material layer 124 a conformally covers the material layer 122 a, in accordance with some embodiments. The material layer 124 a has recesses 124 a 1 in the openings P1, in accordance with some embodiments. The material layers 122 a and 124 a are made of different materials, in accordance with some embodiments. The material layer 122 a is made of titanium or palladium, in accordance with some embodiments. The material layer 124 a is made of copper, in accordance with some embodiments.

In some embodiments, the material layer 122 a is made of titanium, the material layer 124 a is made of copper, and the material layers 122 a and 124 a are formed using a sputtering process. In some embodiments, the material layer 122 a is made of palladium, the material layer 124 a is made of copper, and the material layers 122 a and 124 a are formed using an electroless plating process. The material layers 122 a and 124 a together form a conductive adhesive material layer 120 a, in accordance with some embodiments.

As shown in FIG. 8B, a mask layer 810 is formed over the material layer 124 a, in accordance with some embodiments. The mask layer 810 has openings 812 exposing the material layer 124 a over or adjacent to the pads 115 a, in accordance with some embodiments. The mask layer 810 is made of a photoresist material, such as a polymer material, in accordance with some embodiments.

As shown in FIG. 8B, a nickel layer 820 is formed in the openings 812 and the recesses 124 a 1, in accordance with some embodiments. The recesses 124 a 1 is filled with the nickel layer 820, in accordance with some embodiments. The nickel layer 820 is thicker than the conductive adhesive material layer 120 a, in accordance with some embodiments. That is, a thickness T3 of the nickel layer 820 is greater than a thickness T4 of the conductive adhesive material layer 120 a, in accordance with some embodiments. The thickness T3 ranges from about 3 μm to about 30 in accordance with some embodiments. The thickness T4 ranges from about 0.5 μm to about 2 in accordance with some embodiments.

The nickel layer 820 may prevent copper of the pads 115 a from migrating into conductive bumps, which are subsequently formed over the nickel layer 820, during subsequent high current density operations. Therefore, the nickel layer 820 may reduce electromigration issues.

The nickel layer 820 is made of nickel or an alloy thereof, in accordance with some embodiments. The material layers 122 a and 124 a and the nickel layer 820 are made of different materials, in accordance with some embodiments. The nickel layer 820 is formed using a plating process such as an electroless plating process, in accordance with some embodiments.

As shown in FIG. 8B, a palladium layer 830 is formed over the nickel layer 820, in accordance with some embodiments. The palladium layer 830 is thinner than the nickel layer 820, in accordance with some embodiments. The palladium layer 830 is made of palladium or an alloy thereof, in accordance with some embodiments. The palladium layer 830 is formed using a plating process such as an electroless plating process, in accordance with some embodiments.

As shown in FIG. 8B, a gold layer 840 is formed over the palladium layer 830, in accordance with some embodiments. The gold layer 840 is thinner than the nickel layer 820, in accordance with some embodiments. The gold layer 840 is made of gold or an alloy thereof, in accordance with some embodiments. The gold layer 840 is formed using a plating process such as an immersion plating process, in accordance with some embodiments.

As shown in FIG. 8C, the mask layer 810 and the material layers 122 a and 124 a under the mask layer 810 are removed, in accordance with some embodiments. The material layer 122 a remaining under the nickel layer 820 forms a layer 122, in accordance with some embodiments. The material layer 124 a remaining under the nickel layer 820 forms a layer 124, in accordance with some embodiments. The layers 122 and 124 together form a conductive adhesive layer 120, in accordance with some embodiments.

As shown in FIGS. 8C-8D, the steps of FIGS. 1D-1E and 5A-5B are performed to form the chip 510, the under bump metallurgy layer 520, the conductive bumps 530, the underfill layer U, the adhesive layer 540, and the heat-spreading lid 550 over the wiring substrate 110, in accordance with some embodiments. The palladium layer 830 and the gold layer 840 are dispersed (or dissolved) in the conductive bumps 530 after bonding the chip 510 to the wiring substrate 110, in accordance with some embodiments. The conductive bumps 530 are in direct contact with the nickel layer 820, in accordance with some embodiments.

As shown in FIG. 8D, the step of FIG. 5C is performed to form conductive bumps 560 over the pads 115 b and form chip package structures 800, in accordance with some embodiments. For the sake of simplicity, FIG. 8D only shows one of the chip package structures 800, in accordance with some embodiments.

As shown in FIG. 8D, the step of FIG. 5D is performed to bond the wiring substrate 110 to a wiring substrate 570 through the conductive bumps 560, in accordance with some embodiments. The conductive bumps 560 are between the pads 115 b of the wiring substrate 110 and the pads 578 of the wiring substrate 570, in accordance with some embodiments.

In this step, a chip package structure (or board-level package structure) 801 is substantially formed, in accordance with some embodiments. The chip package structure 801 includes the chip package structure 800, the conductive bumps 560, and the wiring substrate 570, in accordance with some embodiments. The chip package structure 801 is a ball grid array (BGA) package structure, in accordance with some embodiments.

FIGS. 9A-9C are cross-sectional views of various stages of a process for forming a chip package structure, in accordance with some embodiments. As shown in FIG. 9A, after the step of FIG. 8A, a mask layer 910 is formed over the material layer 124 a over or adjacent to the pads 115 a, in accordance with some embodiments. The mask layer 910 is also referred to as a dry film, in accordance with some embodiments. The mask layer 910 is made of a polymer material, in accordance with some embodiments.

As shown in FIGS. 9A-9B, the material layers 122 a and 124 a, which are not covered by the mask layer 910, are removed, in accordance with some embodiments. The material layer 122 a remaining under the mask layer 910 forms a layer 122, in accordance with some embodiments. The material layer 124 a remaining under the mask layer 910 forms a layer 124, in accordance with some embodiments. The layers 122 and 124 together form a conductive adhesive layer 120, in accordance with some embodiments. As shown in FIG. 9B, the mask layer 910 is removed, in accordance with some embodiments.

As shown in FIG. 9B, a nickel layer 920 is formed over the conductive adhesive layer 120, in accordance with some embodiments. The nickel layer 920 covers a top surface 120 a and a sidewall 120 b of the conductive adhesive layer 120, in accordance with some embodiments.

The nickel layer 920 is thicker than the conductive adhesive layer 120, in accordance with some embodiments. That is, a thickness T5 of the nickel layer 920 is greater than a thickness T6 of the conductive adhesive layer 120, in accordance with some embodiments. The thickness T5 ranges from about 3 μm to about 30 in accordance with some embodiments. The thickness T6 ranges from about 0.5 μm to about 2 in accordance with some embodiments.

The nickel layer 920 is made of nickel or an alloy thereof, in accordance with some embodiments. The nickel layer 920 is formed using a plating process such as an electroless plating process, in accordance with some embodiments.

As shown in FIG. 9B, a palladium layer 930 is formed over the nickel layer 920, in accordance with some embodiments. The palladium layer 930 conformally covers a top surface 922 and sidewalls 924 of the nickel layer 920, in accordance with some embodiments. The palladium layer 930 is thinner than the nickel layer 920, in accordance with some embodiments.

The palladium layer 930 is made of palladium or an alloy thereof, in accordance with some embodiments. The palladium layer 930 is formed using a plating process such as an electroless plating process, in accordance with some embodiments.

As shown in FIG. 9B, a gold layer 940 is formed over the palladium layer 930, in accordance with some embodiments. The gold layer 940 conformally covers a top surface 932 and sidewalls 934 of the palladium layer 930, in accordance with some embodiments. The gold layer 940 is thinner than the nickel layer 920, in accordance with some embodiments. The gold layer 940 is made of gold or an alloy thereof, in accordance with some embodiments. The gold layer 940 is formed using a plating process such as an immersion plating process, in accordance with some embodiments.

As shown in FIGS. 9B-9C, the steps of FIGS. 5A-5B are performed to form the chip 510, the under bump metallurgy layer 520, the conductive bumps 530, the underfill layer U, the adhesive layer 540, and the heat-spreading lid 550 over the wiring substrate 110, in accordance with some embodiments. The palladium layer 930 and the gold layer 940 are dissolved in the conductive bumps 530 after bonding the chip 510 to the wiring substrate 110, in accordance with some embodiments.

As shown in FIG. 9C, the step of FIG. 5C is performed to form conductive bumps 560 over the pads 115 b and form chip package structures 900, in accordance with some embodiments. For the sake of simplicity, FIG. 9C only shows one of the chip package structures 900, in accordance with some embodiments.

As shown in FIG. 9C, the step of FIG. 5D is performed to bond the wiring substrate 110 to a wiring substrate 570 through the conductive bumps 560, in accordance with some embodiments. The conductive bumps 560 are between the pads 115 b of the wiring substrate 110 and the pads 578 of the wiring substrate 570, in accordance with some embodiments.

In this step, a chip package structure (or board-level package structure) 901 is substantially formed, in accordance with some embodiments. The chip package structure 901 includes the chip package structure 900, the conductive bumps 560, and the wiring substrate 570, in accordance with some embodiments. The chip package structure 901 is a ball grid array (BGA) package structure, in accordance with some embodiments.

FIGS. 10A-10C are cross-sectional views of various stages of a process for forming a chip package structure, in accordance with some embodiments. As shown in FIG. 10A, after the step of FIG. 8A, a mask layer 1010 is formed over the material layer 124 a, in accordance with some embodiments. The mask layer 1010 has openings 1012 exposing the material layer 124 a over or adjacent to the pads 115 a, in accordance with some embodiments. The mask layer 1010 is made of a photoresist material, such as a polymer material, in accordance with some embodiments.

As shown in FIG. 10A, a nickel layer 1020 is formed in the openings 1012 of the mask layer 1010 and the recesses 124 a 1 of the material layer 124 a, in accordance with some embodiments. The nickel layer 1020 conformally covers the material layer 124 a, in accordance with some embodiments. The nickel layer 1020 has recesses 1022 partially in the recesses 124 a 1, in accordance with some embodiments.

The nickel layer 1020 is thicker than the conductive adhesive material layer 120 a, in accordance with some embodiments. The nickel layer 1020 is made of nickel or an alloy thereof, in accordance with some embodiments. The nickel layer 1020 is formed using a plating process such as an electroless plating process, in accordance with some embodiments.

As shown in FIG. 10A, a copper layer 1030 is formed over the nickel layer 1020 and in the recesses 1022, in accordance with some embodiments. The copper layer 1030 is thicker than the nickel layer 1020, in accordance with some embodiments. The recesses 1022 are filled with the copper layer 1030, in accordance with some embodiments. The copper layer 1030 is made of copper or an alloy thereof, in accordance with some embodiments. The copper layer 1030 is formed using a plating process such as an electroless plating process, in accordance with some embodiments.

As shown in FIGS. 10A-10B, the mask layer 1010 and the material layers 122 a and 124 a under the mask layer 1010 are removed, in accordance with some embodiments. The material layer 122 a remaining under the nickel layer 1020 forms a layer 122, in accordance with some embodiments. The material layer 124 a remaining under the nickel layer 1020 forms a layer 124, in accordance with some embodiments. The layers 122 and 124 together form a conductive adhesive layer 120, in accordance with some embodiments.

As shown in FIG. 10B, a cap layer 1040 is formed over the copper layer 1030, the nickel layer 1020, and the conductive adhesive layer 120, in accordance with some embodiments. The cap layer 1040 conformally covers a top surface 1032 and a sidewall 1034 of the copper layer 1030, a sidewall 1022 of the nickel layer 1020, a sidewall 122 b of the layer 122, and a sidewall 124 b of the layer 124, in accordance with some embodiments. The cap layer 1040 is used to prevent the copper layer 1030, the nickel layer 1020, and the conductive adhesive layer 120 from being oxidized, in accordance with some embodiments.

The cap layer 1040 is made of a material, which is different from that of the copper layer 1030, the nickel layer 1020, and the conductive adhesive layer 120, in accordance with some embodiments. The cap layer 1040 is made of tin or an organic material, in accordance with some embodiments.

The organic material includes an organic solderability preservative (OSP) material, in accordance with some embodiments. The OSP material includes benzotriazole, benzimidazoles, or combinations and derivatives thereof. In some embodiments, the cap layer 1040 is formed by immersing the metal surfaces of the copper layer 1030, the nickel layer 1020, and the conductive adhesive layer 120 in an OSP solution which may contain alkylimidazole, benzotriazole, rosin, rosin esters, or benzimidazole compounds. In some other embodiments, the cap layer 1040 is made of phenylimidazole or other imidazole compounds including 2-arylimidazole as the active ingredient.

As shown in FIGS. 10B-10C, the steps of FIGS. 5A-5B are performed to form the chip 510, the under bump metallurgy layer 520, the conductive bumps 530, the underfill layer U, the adhesive layer 540, and the heat-spreading lid 550 over the wiring substrate 110, in accordance with some embodiments. The conductive bumps 530 are between the copper layer 1030 and the chip 510, in accordance with some embodiments. The cap layer 1040 is dissolved in the conductive bumps 530 after bonding the chip 510 to the wiring substrate 110, in accordance with some embodiments.

As shown in FIG. 10C, the step of FIG. 5C is performed to form conductive bumps 560 over the pads 115 b and form chip package structures 1000, in accordance with some embodiments. For the sake of simplicity, FIG. 10C only shows one of the chip package structures 1000, in accordance with some embodiments.

As shown in FIG. 10C, the step of FIG. 5D is performed to bond the wiring substrate 110 to a wiring substrate 570 through the conductive bumps 560, in accordance with some embodiments. The conductive bumps 560 are between the pads 115 b of the wiring substrate 110 and the pads 578 of the wiring substrate 570, in accordance with some embodiments.

In this step, a chip package structure (or board-level package structure) 1001 is substantially formed, in accordance with some embodiments. The chip package structure 1001 includes the chip package structure 1000, the conductive bumps 560, and the wiring substrate 570, in accordance with some embodiments. The chip package structure 1001 is a ball grid array (BGA) package structure, in accordance with some embodiments.

FIGS. 11A-11C are cross-sectional views of various stages of a process for forming a chip package structure, in accordance with some embodiments. As shown in FIG. 11A, after the step of FIG. 8A, a mask layer 1110 is formed over the material layer 124 a, in accordance with some embodiments. The mask layer 1110 has openings 1112 exposing the material layer 124 a over or adjacent to the pads 115 a, in accordance with some embodiments. The mask layer 1110 is made of a photoresist material, such as a polymer material, in accordance with some embodiments.

As shown in FIG. 11A, a nickel layer 1120 is formed in the openings 1112 of the mask layer 1110 and the recesses 124 a 1 of the material layer 124 a, in accordance with some embodiments. The nickel layer 1120 conformally covers the material layer 124 a, in accordance with some embodiments. The nickel layer 1120 has recesses 1122 partially in the recesses 124 a 1, in accordance with some embodiments.

The nickel layer 1120 is thicker than the conductive adhesive material layer 120 a, in accordance with some embodiments. The nickel layer 1120 is made of nickel or an alloy thereof, in accordance with some embodiments. The nickel layer 1120 is formed using a plating process such as an electroless plating process, in accordance with some embodiments.

As shown in FIG. 11A, a palladium layer 1130 is formed over the nickel layer 1120, in accordance with some embodiments. The palladium layer 1130 is thinner than the nickel layer 1120, in accordance with some embodiments. The palladium layer 1130 is made of palladium or an alloy thereof, in accordance with some embodiments. The palladium layer 1130 is formed using a plating process such as an electroless plating process, in accordance with some embodiments.

As shown in FIG. 11A, a gold layer 1140 is formed over the palladium layer 1130, in accordance with some embodiments. The gold layer 1140 is thinner than the nickel layer 1120, in accordance with some embodiments. The gold layer 1140 is made of gold or an alloy thereof, in accordance with some embodiments. The gold layer 1140 is formed using a plating process such as an immersion plating process, in accordance with some embodiments.

As shown in FIG. 11A, a solder layer 1150 a is formed in the openings 1112 and over the gold layer 1140, in accordance with some embodiments. The solder layer 1150 a is thicker than the nickel layer 1120, in accordance with some embodiments. The solder layer 1150 a is made of tin or an alloy thereof, in accordance with some embodiments. The solder layer 1150 a is formed using a plating process such as an electroplating process or an electroless plating process, in accordance with some embodiments.

As shown in FIGS. 11A-11B, the mask layer 1110 and the material layers 122 a and 124 a under the mask layer 1110 are removed, in accordance with some embodiments. The material layer 122 a remaining under the nickel layer 1120 forms a layer 122, in accordance with some embodiments. The material layer 124 a remaining under the nickel layer 1120 forms a layer 124, in accordance with some embodiments. The layers 122 and 124 together form a conductive adhesive layer 120, in accordance with some embodiments.

As shown in FIG. 11B, a reflow process is performed over the solder layer 1150 a, in accordance with some embodiments. The reflowed solder layer 1150 a forms solder balls 1150, in accordance with some embodiments. The gold layer 1140 and the palladium layer 1130 are dissolved in the solder balls 1150. The solder balls 1150 are in direct contact with the nickel layer 1120, in accordance with some embodiments.

As shown in FIGS. 11B-11C, the steps of FIGS. 5A-5B are performed to form the chip 510, the under bump metallurgy layer 520, the conductive bumps 530, the underfill layer U, the adhesive layer 540, and the heat-spreading lid 550 over the wiring substrate 110, in accordance with some embodiments. The conductive bumps 530 are between the nickel layer 1120 and the under bump metallurgy layer 520, in accordance with some embodiments. A portion of the conductive bumps 530 is formed from the solder balls 1150.

As shown in FIG. 11C, the step of FIG. 5C is performed to form conductive bumps 560 over the pads 115 b and form chip package structures 1100, in accordance with some embodiments. For the sake of simplicity, FIG. 11C only shows one of the chip package structures 1100, in accordance with some embodiments.

As shown in FIG. 11C, the step of FIG. 5D is performed to bond the wiring substrate 110 to a wiring substrate 570 through the conductive bumps 560, in accordance with some embodiments. The conductive bumps 560 are between the pads 115 b of the wiring substrate 110 and the pads 578 of the wiring substrate 570, in accordance with some embodiments.

In this step, a chip package structure (or board-level package structure) 1101 is substantially formed, in accordance with some embodiments. The chip package structure 1101 includes the chip package structure 1100, the conductive bumps 560, and the wiring substrate 570, in accordance with some embodiments. The chip package structure 1101 is a ball grid array (BGA) package structure, in accordance with some embodiments.

Processes and materials for forming the chip package structures 600, 700, 800, 900, 1000 and 1100 may be similar to, or the same as, those for forming the chip package structure 500 described above. Processes and materials for forming the chip package structures 601, 801, 901, 1001 and 1101 may be similar to, or the same as, those for forming the chip package structure 501 described above. Elements designed by the same reference numbers as those in FIGS. 1A to 11C have the structures and the materials similar thereto or the same thereas. Therefore, the detailed descriptions thereof will not be repeated herein.

In accordance with some embodiments, chip package structures and methods for forming the same are provided. The methods (for forming the chip package structure) form a conductive adhesive layer between a wiring substrate and a conductive bump to improve the adhesion between the conductive bump and a polymer layer of the wiring substrate and between the conductive bump and a pad of the wiring substrate. The methods form a nickel layer between the conductive adhesive layer and the conductive bump. The nickel layer prevents materials of the pad from migrating into the conductive bump during high current density operations. Therefore, the nickel layer reduces electromigration issues.

In accordance with some embodiments, a method for forming a chip package structure is provided. The method includes providing a wiring substrate including a substrate, a pad, and a polymer layer. The polymer layer is over the substrate and the pad, and the polymer layer has a first opening exposing the pad. The method includes forming a conductive adhesive layer over the polymer layer and the pad. The conductive adhesive layer is in direct contact with and conformally covers the polymer layer and the pad. The method includes forming a nickel layer over the conductive adhesive layer. The nickel layer is thicker than the conductive adhesive layer, and the nickel layer and the conductive adhesive layer are made of different materials. The method includes bonding a chip to the wiring substrate through a conductive bump. The conductive bump is between the nickel layer and the chip.

In accordance with some embodiments, a method for forming a chip package structure is provided. The method includes providing a wiring substrate including a substrate, a first pad, and a first polymer layer. The first pad is over a first surface of the substrate, the first polymer layer is over the first surface and the first pad, and the first polymer layer has a first opening exposing the first pad. The method includes forming a first conductive adhesive layer over the first polymer layer and the first pad. The first conductive adhesive layer is in direct contact with the first polymer layer and the first pad. The method includes forming a solder structure over the first conductive adhesive layer. The method includes bonding a chip to the wiring substrate through an under bump metallurgy layer and a first conductive bump. The under bump metallurgy layer is between the chip and the first conductive bump, the first conductive bump is connected to the first conductive adhesive layer and the under bump metallurgy layer, a portion of the first conductive bump is formed from the solder structure, and a first thickness of the under bump metallurgy layer is substantially equal to a second thickness of the first conductive adhesive layer.

In accordance with some embodiments, a chip package structure is provided. The chip package structure includes a wiring substrate including a substrate, a first pad, a second pad, and a polymer layer. The first pad and the second pad are respectively over a first surface and a second surface of the substrate, the first pad is narrower than the second pad, and the polymer layer is over the first surface and the first pad. The chip package structure includes a conductive adhesive layer passing through the polymer layer and over the first pad. The conductive adhesive layer is in direct contact with the polymer layer and the first pad. The chip package structure includes a nickel layer over the conductive adhesive layer. The nickel layer is thicker than the conductive adhesive layer, and the nickel layer and the conductive adhesive layer are made of different materials. The chip package structure includes a chip over the wiring substrate. The chip package structure includes a conductive bump between the nickel layer and the chip.

The foregoing outlines features of several embodiments so that those skilled in the art may better understand the aspects of the present disclosure. Those skilled in the art should appreciate that they may readily use the present disclosure as a basis for designing or modifying other processes and structures for carrying out the same purposes and/or achieving the same advantages of the embodiments introduced herein. Those skilled in the art should also realize that such equivalent constructions do not depart from the spirit and scope of the present disclosure, and that they may make various changes, substitutions, and alterations herein without departing from the spirit and scope of the present disclosure. 

What is claimed is:
 1. A method for forming a chip package structure, comprising: providing a wiring substrate comprising a substrate, a pad, and a polymer layer, wherein the polymer layer is over the substrate and the pad, and the polymer layer has a first opening exposing the pad; forming a conductive adhesive layer over the polymer layer and the pad, wherein the conductive adhesive layer is in direct contact with and conformally covers the polymer layer and the pad; forming a nickel layer over the conductive adhesive layer, wherein the nickel layer is thicker than the conductive adhesive layer, and the nickel layer and the conductive adhesive layer are made of different materials; and bonding a chip to the wiring substrate through a conductive bump, wherein the conductive bump is between the nickel layer and the chip.
 2. The method for forming the chip package structure as claimed in claim 1, further comprising: forming a gold layer over the nickel layer before bonding the chip to the wiring substrate, wherein the gold layer is dissolved in the conductive bump after bonding the chip to the wiring substrate.
 3. The method for forming the chip package structure as claimed in claim 2, wherein the forming of the conductive adhesive layer, the nickel layer, and the gold layer comprises: forming a conductive adhesive material layer over the polymer layer and the pad; forming a mask layer over the conductive adhesive material layer, wherein the mask layer has a second opening exposing the conductive adhesive material layer over or adjacent to the pad; forming the nickel layer in the second opening; forming the gold layer over the nickel layer; and removing the mask layer and the conductive adhesive material layer under the mask layer, wherein the conductive adhesive material layer remaining under the nickel layer forms the conductive adhesive layer.
 4. The method for forming the chip package structure as claimed in claim 2, wherein the forming of the conductive adhesive layer comprises: forming a conductive adhesive material layer over the polymer layer and the pad; forming a mask layer over the conductive adhesive material layer over or adjacent to the pad; removing the conductive adhesive material layer, which is exposed by the mask layer, wherein the conductive adhesive material layer remaining under the mask layer forms the conductive adhesive layer; and removing the mask layer.
 5. The method for forming the chip package structure as claimed in claim 4, wherein the gold layer covers a sidewall and a top surface of the nickel layer.
 6. The method for forming the chip package structure as claimed in claim 2, further comprising: after forming the gold layer over the nickel layer, forming a solder ball over the nickel layer, wherein the gold layer is dissolved in the solder ball, and a portion of the conductive bump is formed from the solder ball.
 7. The method for forming the chip package structure as claimed in claim 1, further comprising: forming a copper layer over the nickel layer before bonding the chip to the wiring substrate, wherein the conductive bump is between the copper layer and the chip.
 8. The method for forming the chip package structure as claimed in claim 7, wherein the nickel layer conformally covers the conductive adhesive layer and has a recess partially in the first opening, and the recess is filled with the copper layer.
 9. The method for forming the chip package structure as claimed in claim 8, further comprising: forming a cap layer covering a top surface and a first sidewall of the copper layer, a second sidewall of the nickel layer, a third sidewall of the conductive adhesive layer.
 10. The method for forming the chip package structure as claimed in claim 9, wherein the cap layer is made of tin or an organic material.
 11. A method for forming a chip package structure, comprising: providing a wiring substrate comprising a substrate, a first pad, and a first polymer layer, wherein the first pad is over a first surface of the substrate, the first polymer layer is over the first surface and the first pad, and the first polymer layer has a first opening exposing the first pad; forming a first conductive adhesive layer over the first polymer layer and the first pad, wherein the first conductive adhesive layer is in direct contact with the first polymer layer and the first pad; forming a solder structure over the first conductive adhesive layer; and bonding a chip to the wiring substrate through an under bump metallurgy layer and a first conductive bump, wherein the under bump metallurgy layer is between the chip and the first conductive bump, the first conductive bump is connected to the first conductive adhesive layer and the under bump metallurgy layer, a portion of the first conductive bump is formed from the solder structure, and a first thickness of the under bump metallurgy layer is substantially equal to a second thickness of the first conductive adhesive layer.
 12. The method for forming the chip package structure as claimed in claim 11, wherein the forming of the first conductive adhesive layer and the solder structure comprises: forming a conductive adhesive material layer over the first polymer layer and the first pad; forming a mask layer over the conductive adhesive material layer, wherein the mask layer has a second opening exposing the conductive adhesive material layer over or adjacent to the first pad; forming a solder layer in the second opening; removing the mask layer and the conductive adhesive material layer under the mask layer, wherein the conductive adhesive material layer remaining under the solder layer forms the first conductive adhesive layer; and reflowing the solder layer to form the solder structure.
 13. The method for forming the chip package structure as claimed in claim 11, wherein the forming of the first conductive adhesive layer comprises: forming a conductive adhesive material layer over the first polymer layer and the first pad; forming a first mask layer over the conductive adhesive material layer over or adjacent to the first pad; removing the conductive adhesive material layer exposed by the first mask layer, wherein the conductive adhesive material layer remaining under the first mask layer forms the first conductive adhesive layer; and removing the first mask layer.
 14. The method for forming the chip package structure as claimed in claim 13, wherein the forming of the solder structure over the first conductive adhesive layer comprises: forming a second mask layer over the first polymer layer, wherein the second mask layer has a second opening exposing the first conductive adhesive layer; printing a solder layer in the second opening; removing the second mask layer; and reflowing the solder layer to form the solder structure.
 15. The method for forming the chip package structure as claimed in claim 13, wherein the forming of the solder structure over the first conductive adhesive layer comprises: disposing a solder ball over the first conductive adhesive layer; and reflowing the solder ball to form the solder structure.
 16. The method for forming the chip package structure as claimed in claim 15, further comprising: performing a thermo-compression process over the solder structure to flatten a top surface of the solder structure.
 17. The method for forming the chip package structure as claimed in claim 11, wherein the first conductive adhesive layer is formed using an electroless plating process or a sputtering process.
 18. The method for forming the chip package structure as claimed in claim 11, wherein the wiring substrate further comprises a second pad and a second polymer layer, the second pad is over a second surface of the substrate, the first pad is narrower than the second pad, the second polymer layer is over the second surface and the second pad, and the second polymer layer has a second opening exposing the second pad, and the method further comprises: forming a second conductive adhesive layer over the second polymer layer and the second pad during forming the first conductive adhesive layer over the first polymer layer and the first pad; and forming a second conductive bump over the second conductive adhesive layer after bonding the chip to the wiring substrate.
 19. A chip package structure, comprising: a wiring substrate comprising a substrate, a first pad, a second pad, and a polymer layer, wherein the first pad and the second pad are respectively over a first surface and a second surface of the substrate, the first pad is narrower than the second pad, and the polymer layer is over the first surface and the first pad; a conductive adhesive layer passing through the polymer layer and over the first pad, wherein the conductive adhesive layer is in direct contact with the polymer layer and the first pad; a nickel layer over the conductive adhesive layer, wherein the nickel layer is thicker than the conductive adhesive layer, and the nickel layer and the conductive adhesive layer are made of different materials; a chip over the wiring substrate; and a conductive bump between the nickel layer and the chip.
 20. The chip package structure as claimed in claim 19, wherein the nickel layer covers a sidewall and a top surface of the conductive adhesive layer. 